张军

       张军,男,博士,副教授,硕士生导师。
       2001年6月硕士毕业于华东理工大学,师从钱延龙教授和黄吉玲教授。2006年6月博士毕业于复旦大学,师从金国新教授。随后于2006年10月至2009年9月期间,加入新加坡国立大学化学系Andy Hor教授课题组从事博士后研究工作。期间于2007年10月至2007年12月赴法国Université Louis Pasteur大学Pierre Braunstein教授课题组进行合作研究。2010年3月加入华东理工大学化学与分子工程学院,同年受聘为副教授。自2006年以来,在Nat. Commun., Angew. Chem. Int. Ed., ACS Catal., Coord. Chem. Rev., Chem. Commum., Chem. Asian J., Organometallics, Dalton Trans等国外SCI杂志发表论文三十余篇。

       目前负责包括国家自然科学基金、上海市浦江人才计划、中石化合作等多项科研项目。

       办公室:实验13楼213室,E-mail: zhangj@ecust.edu.cn;Tel: 021-64252995 (o)。 


研究方向:

(1)金属催化有机反应机理研究及关键中间体的分离、表征。

(2)新型氮杂环卡宾配体的设计合成及其在金属催化中的应用。

(3)新型有机金属催化剂的设计合成及其在烯烃聚合中的应用。


研究生招生专业:有机化学。


代表论文:

1.Jiwei Wang, Xiaoming Cao, Shichang Lv, Caiyun Zhang, Sheng Xu, Min Shi, Jun Zhang*, Gold and copper carbenes: the synthesis and structure of active intermediates in gold- or copper-catalyzed amination of alkynes, Nat. Commun., 2017, 8, 14625

2.Caiyun Zhang, Fan Zhang, Shichang Lv, Min Shi, Jun Zhang*, Facile syntheses of N-heterocyclic carbene precursors through Cu(II)- or Ag(I)-catalyzed amination of N-alkynyl formamidines, New J. Chem., 2017, 41, 1889-1892

3.Jiwei Wang, Shichang Lv, Haifeng Chen, Min Shi, and Jun Zhang*, Isolation and characterization of gem-diaurated species having two C–Au σ bonds in gold(I)-activated amidiniumation of alkyne, Dalton Trans., 2016, 45, 17091-17094

4.Wenqi Shen, Jing Li, Caiyun Zhang, Min Shi, and Jun Zhang*, Copper-, silver- and sodium salt-mediated formamidine quaternization of arylation: syntheses of N-heterocyclic carbene precursors and 6-H-phenanthridine derivatives, Chem. Asian J., 2016, 11, 1883-1886

5.Jing Li, Jiajun Jiao, Caiyun Zhang, Min Shi, Jun Zhang*, Facile Syntheses of N-Heterocyclic Carbene Precursors through I2- or NIS-Promoted Amidiniumation of N-Alkenyl Formamidines Chem. Asian J., 2016, 11, 1361-1364

6.Mingfang Zheng, Hongfei Wu, Xuejun Zhang, Jun Zhang*, Heteroscorpionate Bis-pyrazolyl Ligands in Cr(III)-catalyzed Ethylene Oligomerization, J. Organomet. Chem., 2016, 817, 21-25

7.Shichang Lv, Jiwei Wang, Caiyun Zhang, Sheng Xu, Min Shi, and Jun Zhang*, Silver-catalyzed amidiniumation of alkynes: isolation of a silver intermediate, synthesis of enamino amido carbene precursors, and an unprecedented umpolung of propiolamide, Angew. Chem. Int. Ed., 2015, 54, 14941-14946

8.Yusheng Zhou, Hongfei Wu, Sheng Xu, Xuejun Zhang, Min Shi, and Jun Zhang*, Highly active chromium-based selective ethylene tri-/tetramerization catalysts supported by PNPO phosphazane ligands. Dalton Trans., 2015, 44, 9545-9550 

9.Jun Zhang*, Weijie Wu, Xuejun Zhang, Gengtao Zhang, Sheng Xu, and Min Shi, NIS/PhI(OAc)2-mediated diamination/oxidation of N-alkenyl formamidines: facile synthesis of bicyclic ureas, Chem. Asian J., 2015, 10, 544-547

10.Jun Zhang*, Xuejun Zhang, Weijie Wu, Gengtao Zhang, Sheng Xu and Min Shi, Intramolecular aminochalcogenation and diamination of alkenes empolying N-iodosuccinimide, Tetrahedron Lett., 2015, 56, 1505-1509

11.Jun Zhang*, Gengtao Zhang, Weijie Wu, Xuejun Zhang, Min Shi, Metal-free aminoamidiniumation employing N-iodosuccinimide: facile syntheses of bicyclic imidazolidiniums and cyclic vicinal diamines, Chem. Commun., 2014, 50, 15052-15054.

12.Jun Zhang*, Xiao Wang, Xuejun Zhang, Weijie Wu, Gengtao Zhang, Sheng Xu, Min Shi, Switchable Ethylene Tri-/Tetramerization with High Activity: Subtle Effect of Backbone-substituent of Carbon-bridged Diphosphine Ligands, ACS Catalysis, 2013, 3, 2311-2317.

13.Jun Zhang*, Shangfei Song, Xiao Wang, Jiajun Jiao, Min Shi*, Ruthenium-catalyzed olefin metathesis accelerated by the steric effect of the backbone substituent in cyclic (alkyl)(amino) carbenes, Chem. Commun., 2013, 49, 9491-9493.

14.Jun Zhang*, Jun Fu, Xiao Wang, Xiaolong Su, Min Shi*, Synthesis of Various Saturated and Unsaturated N-Heterocyclic Carbene Precursors by Triflic Anhydride Mediated Intramolecular Cyclization, Chem. Asian J., 2013, 8, 552-555.

15.Jun Zhang*, Xinke Qin, Jun Fu, Xiao Wang, Xiaolong Su, Fangle Hu, Jiajun Jiao, Min Shi*, Fine-Tunable 3,4-Dihydroquinazol-2-ylidene Carbenes: Synthesis, Rhodium(I) Complexes, and Reactivity, Organometallics, 2012, 31, 8275-8282.

16.Jun Zhang*, Xiaolong Su, Jun Fu, Xinke Qin, Meixin Zhao, Min Shi*, Tailor-made synthesis of various backbone-substituted imidazolinium salts by triflican hydride mediated intramolecular cyclisation, Chem. Commun., 2012, 48, 9192-9194.

17.Jun Zhang*, Jun Fu, Xiaolong Su, Xinke Qin, Meixin Zhao, Min Shi*, Abnormal oxazol-4-ylidene and thiazol-4-ylidene rhodium complexes: synthesis, structure, and properties, Chem. Commun., 2012, 48, 9625-9627.

18.Jun Zhang*, Xiaolong Su, Jun Fu, Min Shi*, A Facile Preparation of Backbone-substituted, Functionalized and Chiral Imidazolinium Salts, Chem. Commun., 2011, 47, 12541-12543. 

19. Jun Zhang, Peili Teo, Roberto Pattacini, Anthony Kermagoret, Richard Welter, Guillaume Rogez, T. S. Andy Hor and Pierre Braunstein*, Structural effects of sodium cations in polynuclear, multicubane-type mixed Na-Ni complexes, Angew. Chem. Int. Ed., 2010, 49, 4443-4446. 

20.Jun Zhang, Aifang Li, and T. S. Andy Hor*, Crystallographic Revelation of the Role of AlMe3 (in MAO) in Cr-[NNN] Pyrazolyl Catalysed Ethylene Trimerisation, Organometallics, 2009, 28, 2935.

21.Jun Zhang, Aifang Li, T. S. Andy Hor*, Ethylene Trimerisation with [NNN] Heteroscorpionate Pyrazolyl Cr(III) Catalysts: Effect of Ligand Structure on Activity and Selectivity, Dalton Trans., 2009, 38, 9327-9333.

22.Jun Zhang, Yue-Jian Lin, Guo-Xin Jin*, Synthesis, characterization, and ethylene polymerization of group IV metal complexes with mono-Cp and tridentate aryloxide or arylsulfide ligands, Organometallics, 2007, 26, 4042-4047.

23.Jun Zhang, Xin Wang, Guo-Xin Jin, Polymerized metallocene catalysts and late transition metal catalysts for ethylene polymerization, Coord. Chem. Rev., 2006, 250, 95-109

24.Jun Zhang, Guangrong Tang, Guo-xin Jin, Half-sandwich beta-diketonato complexes of zirconium and their application as catalysts to ethylene polymerization, Chinese Sci. Bull., 2006, 51, 2964-2972   

25.Jun Zhang, Guo-Xin Jin, Self-immobilized and polymerized miscellaneous metallocene catalysts for ethylene polymerization, Inorg. Chem. Commun. 2006, 9, 683-686